281 research outputs found
Study of improved resins for advanced supersonic technology composites. Part 1: Heteroaromatic polymers containing ether groups. Part 2: Curing chemistry of aromatic polymers and composite studies
Fourteen ether-containing, aromatic dianhydrides have been synthesized from N-phenyl-3 or 4-nitrophthalimide and various bisphenols. The process involves nucleophilic displacement of activated nitro groups with bisphenolate ions. Ether-containing dianhydrides were indefinitely stable in the presence of atmospheric moisture. One-step, high temperature solution polymerization of the ether-containing dianhydrides with m-phenylene diamine, 4,4'-oxydianiline and 1, 3-bis(4-aminophenoxy)benzene afforded 42 polyetherimides. The polyetherimides were all soluble in m-cresol except two which were found to be crystalline. The glass transition temperatures of the polyetherimides ranged from 178 to 277 C. Soluble polybenzimidazopyrrolones containing ether groups were also prepared from the same ether-containing dianhydrides and aromatic tetraamines by one-step solution polymerization. Using low molecular weight polyetherimides, various thermoset resin systems were developed and tested as matrices for fiber-reinforced composites. The curing chemistry involving reaction of the phthalonitrile group and the o-diaminophenyl group was found to be generally applicable to crosslinking various aromatic polymers other than polyimides
Fictitious Magnetic Resonance by Quasi-Electrostatic Field
We propose a new kind of spin manipulation method using a {\it fictitious}
magnetic field generated by a quasi-electrostatic field. The method can be
applicable to every atom with electron spins and has distinct advantages of
small photon scattering rate and local addressability. By using a
laser as a quasi-electrostatic field, we have experimentally demonstrated the
proposed method by observing the Rabi-oscillation of the ground state hyperfine
spin F=1 of the cold atoms and the Bose-Einstein condensate.Comment: 5 pages, 5 figure
Very long storage times and evaporative cooling of cesium atoms in a quasi-electrostatic dipole trap
We have trapped cesium atoms over many minutes in the focus of a CO-laser
beam employing an extremely simple laser system. Collisional properties of the
unpolarized atoms in their electronic ground state are investigated. Inelastic
binary collisions changing the hyperfine state lead to trap loss which is
quantitatively analyzed. Elastic collisions result in evaporative cooling of
the trapped gas from 25 K to 10 K over a time scale of about 150 s.Comment: 5 pages, 3 figure
Hyperfine, rotational and Zeeman structure of the lowest vibrational levels of the Rb \tripletex state
We present the results of an experimental and theoretical study of the
electronically excited \tripletex state of Rb molecules. The
vibrational energies are measured for deeply bound states from the bottom up to
using laser spectroscopy of ultracold Rb Feshbach molecules. The
spectrum of each vibrational state is dominated by a 47\,GHz splitting into a
\cog and \clg component caused mainly by a strong second order spin-orbit
interaction. Our spectroscopy fully resolves the rotational, hyperfine, and
Zeeman structure of the spectrum. We are able to describe to first order this
structure using a simplified effective Hamiltonian.Comment: 10 pages, 7 figures, 2 table
Molecular vibration in cold collision theory
Cold collisions of ground state oxygen molecules with Helium have been
investigated in a wide range of cold collision energies (from 1 K up to 10
K) treating the oxygen molecule first as a rigid rotor and then introducing the
vibrational degree of freedom. The comparison between the two models shows that
at low energies the rigid rotor approximation is very accurate and able to
describe all the dynamical features of the system. The comparison between the
two models has also been extended to cases where the interaction potential He -
O is made artificially stronger. In this case vibration can perturb rate
constants, but fine-tuning the rigid rotor potential can alleviate the
discrepancies between the two models.Comment: 11 pages, 3 figure
Quantum entanglement using trapped atomic spins
We propose an implementation for quantum logic and computing using trapped
atomic spins of two different species, interacting via direct magnetic
spin-spin interaction. In this scheme, the spins (electronic or nuclear) of
distantly spaced trapped neutral atoms serve as the qubit arrays for quantum
information processing and storage, and the controlled interaction between two
spins, as required for universal quantum computing, is implemented in a three
step process that involves state swapping with a movable auxiliary spin.Comment: minor revisions with an updated discussion on adibatic tranportation
of trapped qubit, 5 pages, 3 figs, resubmitted to PR
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